関連論文

1. ゼオライト膜
  (1) MCM-22膜(水熱合成法)
  (2) シリカライト膜(水熱合成法)
  (3) ZSM-5膜(ドライゲルコンバージョン法)
  (4)水素分離膜(溶解法)
2. メソポーラスシリカ分離膜
  (1) 親水製膜(ジルコニウム含有)
  (2) 疎水性膜(有機シリル化)
3. ゼオライト触媒(低級オレフィン合成)
  (1) SAPO-34ナノ粒子
  (2) ZSM-5触媒
4. 反応分離型触媒
  (1) p-キシレン合成
  (2) コアシェル型ゼオライトコンポジット(p-キシレン合成)
  (3) 水素化
  (4) FT合成
5. メソポーラスシリカ薄膜(Low-k, Low-index)
  (1) 蒸気浸透法
  (2) 蒸気合成法
  (3)メソポーラスリン酸塩薄膜(プロトン導電性)
6. ミクロポーラスカーボン
  (1) 分離膜
  (2) カーボン粒子
7. 規則性メソポーラスカーボン
8. 酸化亜鉛(水熱合成)

 

1. ゼオライト膜
(1) MCM-22膜(水熱合成法)
K. Makita, Y. Hirota, Y. Egashira, K. Yoshida, Y. Sasaki, N. Nishiyama, “Synthesis of MCM-22 zeolite membranes and vapor permeation of water/acetic acid mixtures”, J. Membr. Sci., 372, 269-276. (2011)

(2) シリカライト膜(水熱合成法)
N. Nishiyama, L. Gora, V. Teplyakov, F. Kapteijn and J. A. Moulijn, “Evaluation of reproducible high flux silicalite-1 membranes: Gas permeation and separation characterization”, Sep. Purif. Technol., 22-23, 295-307 (2001)

(3) ZSM-5膜(ドライゲルコンバージョン法)
M. Matsukata, N. Nishiyama and K. Ueyama, “Synthesis of zeolites under vapor atmosphere: Effect of synthetic conditions on a zeolite structure”, Micropor. Mater., 1, 219-222 (1993)

T. Matsufuji, N. Nishiyama, M. Matsukata and K. Ueyama, “Separation of butane and xylene isomers with MFI-type zeolitic membrane synthesized by a vapor-phase transport method”, J. Membr. Sci., 178, 25-34 (2000)

T. Matsufuji, K. Watanabe, N. Nishiyama, M. Matsukata and K. Ueyama, “Permeation of hexane isomers through an MFI membrane”, Ind. Eng. Chem. Res., 39, 2434-2438 (2000)

N. Nishiyama, K. Ueyama and M. Matsukata, “Gas permeation through zeolitic-alumina composite membranes”, AIChE J., 43, 2724-2730 (1997)

(4)水素分離膜(溶解法)

N. Nishiyama, M. Yamaguchi, T. Katayama, Y. Hirota, M. Miyamoto, Y. Egashira, K. Ueyama, K. Nakanishi, T. Ohta, A. Mizusawa, T. Satoh, “Hydrogen-permeable membranes composed of zeolite nano-blocks”, J. Membr. Sci., 306, 349–354 (2007)

2. メソポーラスシリカ分離膜

(1) 親水製膜(ジルコニウム含有)

N. Nishiyama, D.-H. Park, Hens Saputra, Y. Egashira and K. Ueyama, “Zirconium-containing mesoporous silica Zr-MCM-48 for alkali resistant filtration membranes”, J. Membr. Sci., 218, 165-171 (2003)

D.-H. Park, M. Matsuda, N. Nishiyama, Y. Egashira and K. Ueyama, “Zirconium-containing mesoporous silica with high alkaline resistance”, J. Chem. Eng. Japan, 34, 1321-1324 (2001)

(2) 疎水性膜(有機シリル化)

シリル化D.-H. Park, N. Nishiyama, Y. Egashira, K. Ueyama, “Separation of Organic/water Mixtures with Silylated MCM-48 Silica Membranes”, Micropor. Mesopor. Mater., 66, 69-76 (2003)

D.-H. Park, N. Nishiyama, Y. Egashira and K. Ueyama, “Enhancement of hydrothermal stability and hydrophobicity of a silica MCM-48 membrane by silylation”, Ind. Eng. Chem. Res., 40, 6105-6110 (2001)

3. ゼオライト触媒(低級オレフィン合成)

(1) SAPO-34ナノ粒子

Y. Hirota, K. Murata, S. Tanaka, N. Nishiyama, Y. Egashira, K. Ueyama, “Dry gel conversion synthesis of SAPO-34 nanocrystals”, Mater. Chem. Phys., 123, 507–509 (2010)

Y. Hirota, K. Murata, M. Miyamoto, Y. Egashira, N. Nishiyama, “Light olefins synthesis from methanol and dimethylether over SAPO-34 nanocrystals”, Cat. Lett., 140, 22-26 (2010)

(2) ZSM-5触媒

D. Van Vu, Y. Hirota, N. Nishiyama, Y. Egashira, K. Ueyama, “High propylene selectivity in methanol-to-olefin reaction over H-ZSM-5 catalyst treated with phosphoric acid”, J. Jpn. Petrol. Inst., 53, 232-238 (2010)

4. 反応分離型触媒

(1) p-キシレン合成

N. Nishiyama, M. Miyamoto, Y. Egashira and K. Ueyama, “Zeolite membrane on catalyst particle for selective formation of p-xylene in disproportionation of toluene”, Chem. Commun., 1746-1747 (2001)

(2) コアシェル型ゼオライトコンポジット(p-キシレン合成)

M. Miyamoto, T. Kamei, N. Nishiyama, Y. Egashira and K. Ueyama, “Single Crystals of ZSM-5/silicalite Composites”, Adv. Mater., 17, 1985-1988 (2005)

D. Van Vu, M. Miyamoto, N. Nishiyama, Y. Egashira, K. Ueyama, “Selective formation of para-Xylene over H-ZSM-5 coated with polycrystalline silicalite crystals”, J. Catal., 243, 389-394 (2006)

(3) 水素化

N. Nishiyama, K. Ichioka, D.-H. Park, Y. Egashira, K. Ueyama, L. Gora, W. Zhu, F. Kapteijn, and J. A. Moulijn,Reactant selective hydrogenation over composite silicalite-1-coated Pt/TiO2 particles”, Ind. Eng. Chem. Res., 43, 1211-1215 (2004)

(4) FT合成

J. He, Y. Yoneyama, B. Xu, N. Nishiyama and N. Tsubaki, “Designing Capsule Catalyst and Its Application for Direct Synthesis of Middle Isoparaffins”, Langmuir, 21, 1699-1702 (2005)

5. メソポーラスシリカ薄膜(Low-k, Low-index)

(1) 蒸気浸透法

N. Nishiyama, S. Tanaka, Y. Egashira, Y. Oku, K. Ueyama, “Enhancement of structural stability of mesoporous silica thin films prepared by spin coating”, Chem. Mater., 14, 4229-4234 (2002)

S. Tanaka, J. Kaihara, N. Nishiyama, Y. Oku, Y. Egashira and K. Ueyama, “Incorporation of organic groups within the channel wall of spin-on mesostructured silica films by a vapor infiltration technique”, Langmuir, 20 (9), 3780-3784 (2004)

S. Tanaka, H. Tada, T. Maruo, N. Nishiyama, Y. Egashira, K. Ueyama, “Vapor Infiltration techniques for Spin-On Mesoporous Silica Films”, Thin Solid Film, 495, 186-190 (2006)

T. Maruo, S. Tanaka, N. Nishiyama, K. Motoda, K. Funayama, Y. Egashira, K. Ueyama, “Low-index mesoporous silica films modified with trimethylethoxysilane”, Colloids and Surfaces A, 318, 84-87 (2008)

(2) 蒸気合成法

N. Nishiyama, S. Tanaka, Y. Egashira, Y. Oku, K. Ueyama, “Vapor phase synthesis of mesoporous silica thin films”, Chem. Mater., 15, 1006-1011 (2003)

S. Tanaka, N. Nishiyama, Y. Oku, Y. Egashira and K. Ueyama, “Nano-Architectural Silica Thin Films with Two-Dimensionally Connected Cage-Like Pores Synthesized from Vapor Phase”, J. Am. Chem. Soc., 126 (15), 4854-4858 (2004)

S. Tanaka, N. Nishiyama, Y. Hayashi, Y. Egashira and K. Ueyama, “Ultrathin Silica Films with Nanoporous Monolayer”, Chem. Lett., 33 (11), 1408-1409 (2004)

D. B. Cassidy, S. H. M. Deng, R. G. Greaves, T. Maruo, N. Nishiyama, J. B. Snyder, H. K. M. Tanaka, and A. P. Mills, Jr., “Experimentals with a high-density positronium gas”, Phys. Rev. Lett., 95 (19), 195006 (2005)

(3)メソポーラスリン酸塩薄膜(プロトン導電性)

Y. Nishiyama, K. Ochi, N. Nishiyama, Y. Egashira, K. Ueyama, “Proton-conducting mesoporous silica/phosphate composite films prepared by vapor phase method”, Electrochemical and Solid-State Letters, 11, B6-B9 (2008)

N. Nishiyama, J. Kaihara, Y. Nishiyama, Y. Egashira, K. Ueyama, “Vapor Phase Synthesis of Mesoporous SiO2-P2O5 Thin Films”, Langmuir, 23, 4746-4748(2007)

6. ミクロポーラスカーボン

(1) 分離膜

N. Nishiyama, W. Momose, Y. Egashira and K. Ueyama, “Partially carbonized polyimide membranes with high permeability for air separation”, J. Chem. Eng. Japan, 36, 603-608 (2003)

N. Nishiyama, Y.-R. Dong, T. Zheng, Y. Egashira, K. Ueyama, “Tertiary amine-mediated synthesis of microporous carbon membranes”, J. Membr. Sci., 280, 603-609 (2006)

Y.-R. Dong, N. Nishiyama, Y. Egashira, K. Ueyama, “H2-selective carbon membranes prepared from furfuryl alcohol by vapor phase synthesis”, Ind. Eng. Chem. Res., 46, 4040-4044 (2007)

(2) カーボン粒子

Y.-R. Dong, N. Nishiyama, M. Kodama, Y. Egashira, K. Ueyama, “Nitrogen-containing microporous carbons prepared from anionic surfactant-melamine/formaldehyde composites”, Carbon, 47, 2138-2141 (2009)

Y.-R. Dong, N. Nishiyama, Y. Egashira, K. Ueyama, “Basic amino acid-assisted synthesis of resorcinol- formaldehyde polymer and carbon nanospheres”, Ind. Eng. Chem. Res., 47, 4712-4718 (2008)

N. Nishiyama, T. Zheng, Y. Yamane, Y. Egashira and K. Ueyama, “Microporous carbons prepared from cationic surfactant-resorcinol/formaldehyde composites”, Carbon, 43, 269-274 (2005)

7. 規則性メソポーラスカーボン

S. Tanaka, N. Nishiyama, Y. Egashira, K. Ueyama, “Synthesis of ordered mesoporous carbons with channel structure from an organic-organic nanocomposite”, Chem. Commun., 2005 (16), 2125-2127 (2005)

J. Jin, N. Nishiyama, Y. Egashira, K. Ueyama, “Pore structure and pore size controls of ordered mesoporous carbons prepared from resorcinol/formaldehyde/triblock polymers”, Micropor. Mesopor. Mater., 118, 218-223 (2009)

J. Jin, N. Nishiyama, Y. Egashira, K. Ueyama, “Vapor phase synthesis of ultrathin carbon films with a mesoporous monolayer by a soft-templating method”, Chem. Commun., 2009 (11), 1371-1373 (2009)

J. Jin, S. Tanaka, Y. Egashira, N. Nishiyama, “KOH activation of ordered mesoporous carbons prepared by a soft-templating method and their enhanced electrochemical properties”, Carbon, 48, 1985-1989 (2010)

8. 酸化亜鉛(水熱合成)

N. Ueno, T. Maruo, N. Nishiyama, Y. Egashira, K. Ueyama, “Low temperature synthesis of ZnO nanorods using a seed layer of zinc acetate/sodium dodecyle sulfate nanocomposite”, Mater. Lett., 64, 513-515(2010)