池田聡君(M2)の論文がChemCatChem誌の表紙を飾ることが決まりました!
池田聡君(M2)の論文がChemCatChem誌の表紙を飾ることが決まりました!
ChemCatChem誌では特に質が高いと評価された論文のイメージ図が表紙として掲載されます。
論文のタイトル
"Simple and Efficient 1,3-Isomerization of Allylic Alcohols Using Supported Monomeric Vanadium Oxide Catalyst"
T. Mitsudome, S. Sueoka, S. Ikeda, T. Mizugaki, K. Jitsukawa, K. Kaneda
http://onlinelibrary.wiley.com/doi/10.1002/cctc.201300200/abstract
↓池田氏作
内容
The cover picture shows that an isolated monomeric vanadium-oxide species can promote the isomerization of allylic alcohols under liquid-phase conditions. In this Communication, we present creation and characterization of the isolated monomeric vanadium species on silica surface (V/SiO2) and the high catalytic activity of V/SiO2 for various allylic alcohols, including under scaled-up and solvent-free reaction conditions. This heterogeneous catalyst can also exhibit high reusability with no drop in activity. Our results highlight the monomeric vanadium species plays a crucial role in the isomerization.