雑誌表紙

         


 

発表論文/著書 


2017年

5) New Routes for Refinery of Biogenic Platform Chemicals Catalyzed by Cerium Oxide-supported Ruthenium Nanoparticles in Water

Scientific Reports, 2017, 7, 14007.

T. Mizugaki, K. Togo, Z. Maeno, T. Mitsudome, K. Jitsukawa, K. Kaneda

論文は無料で閲覧可能です!  http://resou.osaka-u.ac.jp/ja/research/2017/20171026_2

プレスリリースしました!  http://resou.osaka-u.ac.jp/ja/research/2017/20171026_2


4) A Dual-functional Heterogeneous Ruthenium Catalyst for the Green One-pot Synthesis of Biphenols

Catal. Sci. Tech. 2017, 7, 3205-3209.

Z. Maeno, T. Mitsudome, T. Mizugaki, K. Jitsukawa


3) Mild Hydrogenation of Amides to Amines over Platinum-Vanadium Bimetallic Catalyst

  Angew. Chem. Int. Ed. 2017, 56, 9381-9385.

T. Mitsudome, K. Miyagawa,  Z. Maeno,  T. Mizugaki, K. Jitsukawa, J. Yamasaki, Y. Kitagawa, K. Kaneda

http://onlinelibrary.wiley.com/doi/10.1002/anie.201704199/full

SYNFACTS (2017, 13, 1210)に選定されました!

2) A Titanium Dioxide-supported Gold Nanoparticle Catalyst for the Selective N-Formylation of Functionalized Amines with CO2 and H2

  ChemCatCem 2017, 9, 3632-3636

T. Mitsudome, T. Urayama, S. Fujita, Z. Maeno,  T. Mizugaki, K. Jitsukawa, K. Kaneda

https://doi.org/10.1002/cctc.201700726

Selected in Cover !!

https://doi.org/10.1002/cctc.201701520




1) Effective Management of Polyethers through Depolymerization to Symmetric and Unsymmetric Glycol Diesters Using Proton-exchanged Montmorillonite Catalyst  

Green Chemistry, 2017, 19, 2612 - 2619

Z. Maeno, S. Yamada, T. Mitsudome, T. Mizugaki, K. Jitsukawa


                      

2016年

5) On-demand Hydrogen Production from Organosilanes at Ambient Temperature Using Heterogeneous Gold Catalysts

Scientific Reports, 2016, 6, 37682.

T. Mitsudome, T. Urayama, T. Kiyohiro, Z. Maeno, T. Mizugaki, K. Jitsukawa, K. Kaneda


水素が生成する動画↓

https://youtu.be/vqJ10GH0izY

論文は無料で閲覧可能です↓

http://www.nature.com/articles/srep37682


プレスリリースしました↓

http://resou.osaka-u.ac.jp/ja/research/2016/20161124_2

プレス発表↓

・朝日新聞11月25日(夕刊11面)
"廃棄物+水→水素発生~阪大グループが新技術~”

・日刊工業新聞11月28日「科学技術・大学」面(20頁)
"阪大、廃棄物と水から水素生成する触媒開発−携帯型発生装置開発へ

・大学ジャーナルオンライン11月30日URL http://univ-journal.jp/10752/
"大阪大学、廃棄物と水から水素を生成する触媒技術を開発"

・産経新聞ネット版12月3日付【坂口至徳の科学の現場を歩く】URL http://www.sankei.com/west/news/161203/wst1612030007-n1.html
"画期的モバイル電源に…水素を廃棄物から生成する触媒技術、阪大が世界初提案"


  

4) Green, Multi-Gram One-Step Synthesis of Core–Shell Nanocomposites in Water and Their Catalytic Application to Chemoselective Hydrogenations

Chemistry A European Journal, 2016, 22, 17962 -17966.

T. Urayama, T. Mitsudome, Z. Maeno, T. Mizugaki, K. Jitsukawa, K. Kaneda

http://dx.doi.org/10.1002/chem.201604763

Selected as a Highlight Paper with Frontispiece

Selected for "Synfact of month" and Cover of Synfacts (issue 03/2017)





3) Synthesis of Tetraline Derivatives through Depolymerization of Polyethers with Aromatic Compounds Using Heterogeneous Titanium-Exchanged Montmorillonite Catalyst

RSC Advances, 20166, 89231 - 89233.

Z. Maeno, H. Torii, S. Yamada, T. Mitsudome, T. Mizugaki, K. Jitsukawa


2) One-pot Transformation of Levulinic Acid to 2-Methyltetrahydrofuran Catalyzed by Pt-Mo/H-beta in Water

ACS Sustainable Chemistry & Engineering, 2016, 4(3), 682-685.

T. Mizugaki, K. Togo, Z. Maeno, T. Mitsudome, K. Jitsukawa, K. Kaneda

DOI:10.1021/acssuschemeng.6b00181

1) Depolymerization of Polyethers to Chloroesters Using Heterogeneous Proton-exchanged Montmorillonite Catalyst

ChemistrySelect, 2016, 1, 201-204.

Z. Maeno, S. Yamada, T. Mitsudome, T. Mizugaki, K. Jitsukawa


 

2015年

6) Design of Core-Pd/Shell-Ag Nanocomposite Catalyst for Selective Semihydrogenation of Alkynes

ACS Catalysis, 2016, 6, 666-670

T. Mitsudome, T. Urayama, K. Yamazaki, Y. Maehara, J. Yamasaki, K. Gohara, Z. Maeno, T. Mizugaki, K. Jitsukawa, K. Kaneda 

http://pubs.acs.org/doi/abs/10.1021/acscatal.5b02518

Selected by Synfacts (issue 12/2016)

5) One-step Synthesis of Core-Gold/Shell-Ceria Nano-material and Its Catalysis for Highly Selective Semihydrogenation of Alkynes

J. Am. Chem. Soc., 2015, 137, 13452-13455.     

T. Mitsudome, M. Yamamoto, Z. Maeno, T. Mizugaki, K. Jitsukawa, K. Kaneda

http://pubs.acs.org/doi/full/10.1021/jacs.5b07521

Selected by Synfacts (issue 02/2016)



4) Selective Hydrogenation of Levulinic Acid to 1,4-Pentanediol in Water Using a Hydroxyapatite-supported Pt-Mo Bimetallic Catalyst

Green Chem., 2015, 17, 5136-5139.

T. Mizugaki, Y. Nagatsu, K. Togo, Z. Maeno, T. Mitsudome, K. Jitsukawa, K. Kaneda

DOI: 10.1039/c5gc01878a

Selected in Inside Back Cover !!




3) O2-enhanced Catalytic Activity of Gold Nanoparticles in Selective Oxidation of Hydrosilanes to Silanols

Chem. Lett., 2015, 44(8), 1062-1064

T. Urayama, T. Mitsudome, Z. Maeno, T. Mizugaki, K. Jitsukawa, K. Kaneda

Selected by Synfacts (issue 11/2015)



2) "Selective C-C Coupling Reaction of Dimethylphenol to Tetramethyldiphenoquinone Using Molecular Oxygen Catalyzed by Cu Complexes immobilized in Nanospaces of Structurally-ordered Materials"

Molecules, 2015, 20(2), 3089-3106

Z. Maeno, T. Mitsudome, T. Mizugaki, K. Jitsukawa, K. Kaneda

1) "Highly Efficient Dehydrogenative Coupling of Hydrosilanes with Amines or Amides Using Suppoprted Gold Nanoparticle"

Chem. Eur. J. 2015, 21(8), 3202-3205. 

T. Mitsudome, T. Urayama, Z. Maeno, T. Mizugaki, K. Jitsukawa, K. Kaneda

Selected by Synfacts (issue 05/2015)

2014年

5) "Direct Transformation of Furfural to 1,2-Pentandiol Using a Hydrotalcite-Supported Platinum Nanoparticle Catalyst"

ACS Sustainable Chemistry & Engineering, 2014, 2(10), 2243-2247.

T. Mizugaki, T. Yamakawa, Y. Nagatsu, Z. Maeno, T. Mitsudome, K. Jitsukawa, K. Kaneda

Doi: 10.1021/sc500325g


4) "Hydrogenation of Sulfoxides to sulfides under Mild Conditions Using Ru Nanoparticle Catalysts"

Angew. Chem. Int. Ed. 2014, 53, 8348-8351

T. Mitsudome, Y. Takahashi, T. Mizugaki, K. Jitsukawa, K. Kaneda

http://onlinelibrary.wiley.com/doi/10.1002/anie.201403425/abstract

Selected by Synfacts (issue 11/2014) !!

3) "Selective Synthesis of Rh5 Carbonyl Clusters within a Polyamine Dendrimer for Chemoselective Reduction of Nitro Aromatics"

Chem. Commun. 2014, 50(49), 6526-6529. 

Z. Maeno, T. Mitsudome, T. Mizugaki, K. Jitsukawa, K. Kaneda

http://pubs.rsc.org/en/content/articlelanding/2014/cc/c4cc00976b

Selected by Synfacts (issue 08/2014) !!

2) "Highly Efficient and Selective Transformations of Glycerol Using Reusable  Heterogeneous Catalysts"

ACS Sustainable Chemistry & Engineering, 2014, 2 (14), 574-578.

 Featured in ACS Editors' Choice (February 3, 2014),  Selected as cover article !

T. Mizugaki, R. Arundhathi, T. Mitsudome, K. Jitsukawa, K. Kaneda

DOI: 10.1021/sc500006b


1) "Highly Efficient Deoxygenation of Sulfoxide Using Hydroxyapatite-supported Ruthenium Nanoparticles"

Chem. Lett. 2014, 43, 420-422. 

Y. Takahashi, T. Mitsudome, T. Mizugaki, K. Jitsukawa, K. Kaneda

2013年

18)  "担体をマクロリガンドとした貴金属ナノ粒子触媒の開発”

触媒 2013, Vol. 55, No. 4, 188-194. 

満留敬人, 水垣共雄, 實川浩一郎, 金田清臣

 

17)  "Highly Efficient Etherification of Silanes Using Gold Nanoparticle Catalyst~Remarkable Effect of O2~

Chem. Eur. J. 2013, 19, 14398-14402.

Selected as a Highlight Paper with Frontispiece!

T. Mitsudome, Y. Yamamoto, A. Noujima, T. Mizugaki, K. Jitsukawa, K. Kaneda

http://onlinelibrary.wiley.com/doi/10.1002/chem.201302807/abstract

16)   Coinage metal nanoparticles on hydrotalcite. In Electronic Encyclopedia of Reagents for Organic Synthesis, Wiley: 2013

K. Kaneda, T. Mitsudome

 

15)  Book "Oxidation of Alcohols Using Nano-Catalysts" In Nano-Catalysis Synthesis and Applications, Polshettiwar, V.; Asefa, T., Eds. 2013,  John Wiley & Sons

T. Mitsudome, K. Kaneda

 

14)  Review "Gold Nanoparticle Catalysts for Selective Hydrogenations"

Green Chem. 2013, 15, 2636-2654

T. Mitsudome, K. Kaneda

http://pubs.rsc.org/en/content/articlelanding/2013/gc/c3gc41360h


 13)  "Highly Atom-Efficient and Chemoselective Reduction of Ketones in the Presence of Aldehydes Using Heterogeneous Catalysts"

Green Chem. 2013, 15, 2695-2698.

Y. Takahashi, T. Mitsudome, T. Mizugaki, K. Jitsukawa, K. Kaneda

http://pubs.rsc.org/en/content/articlelanding/2013/gc/c3gc41322e

 

 

12)  "Highly Selective Hydrogenolysis of Glycerol to 1,3-Propanediol over a Boehmite-Supported Platinum/Tungsten Catalyst"

ChemSusChem 2013, 6, 1345-1347.

R. Arundhathi, T. Mizugaki, T. Mitsudome, K. Jitsukawa, K. Kaneda

http://onlinelibrary.wiley.com/doi/10.1002/cssc.201300196/abstract;jsessionid=C7347C87323DBF266816C3D388E4332E.d03t02

11)  "Simple and Efficient 1,3-Isomerization of Allylic Alcohols Using Supported Monomeric Vanadium Oxide Catalyst" 

ChemCatChem 2013, 5, 2879-2882.

T. Mitsudome, S. Sueoka, S. Ikeda, T. Mizugaki, K. Jitsukawa, K. Kaneda

http://onlinelibrary.wiley.com/doi/10.1002/cctc.201300200/abstract

Selected as Back Cover !

http://onlinelibrary.wiley.com/doi/10.1002/cctc.201390052/abstract

10) "Regioselective Oxidative Coupling of 2,6-Dimethylphenol to Tetramethyldiphenoquinone Using Polyamine Dendrimer-encapsulated Cu Catalysts",

RSC Adv. 2013, 3, 5961-5964.

Z. Maeno, M. Okao, T. Mitsudome, T. Mizugaki, K. Jitsukawa, K. Kaneda

http://pubs.rsc.org/en/content/articlelanding/2013/ra/c3ra41817k

9) "Selective Hydrogenolysis of Glycerol to 1,2-Propanediol Using Heterogeneous Copper Nanoparticle Catalyst Derived from Cu-Al Hydrotalcite",

Chem. Lett. 2013, 42, 729-731.

 T. Mizugaki, R. Arundhathi, T. Mitsudome, K. Jitsukawa, K. Kaneda

 

8) "Highly Atom-Efficient Oxidation of Electron-Deficient Internal Olefins to Ketones Using Pd catalyst",

Angew. Chem. Int. Ed. 2013, 52, 5961-596.

T. Mitsudome, S. Yoshida, T. Mizugaki, K. Jitsukawa, K. Kaneda

http://onlinelibrary.wiley.com/doi/10.1002/anie.201301611/abstract

7) "Remarkable Effect of Bases on Core-Shell AgNP@CeO2 Nanocomposite-Catalyzed Highly Chemoselective Reductions of Unsaturated Aldehydes",

Chem. Lett. 2013, 42, 660-662.

Selected in Editor's Choice!

T. Mitsudome, M. Matoba, M. Yamamoto, T. Mizugaki, K. Jitsukawa, K. Kaneda

https://www.jstage.jst.go.jp/article/cl/advpub/0/advpub_130132/_article

 

6) Review "Advanced Core-Shell Nanoparticle Catalysts for Efficient Organic Transformations",

ChemCatChem, 2013, 5, 1681-1691.

T. Mitsudome,  K. Kaneda

http://onlinelibrary.wiley.com/doi/10.1002/cctc.201200724/abstract

 

5) "Size Selective Synthesis of Subnano Pd Clusters using Core[poly(propylene imine)]-shell[poly(benzyl ether)] Hybrid Dendrimers",

Chem. Lett. 2003, 42, 313-315.

T. Mizugaki, T. Kibata, T. Mitsudome, K. Jitsukawa, K. Kaneda

http://www.csj.jp/journals/chem-lett/cl-cont/cl2013-3.html


4) "Core-Shell AgNP@CeO2 Nanocomposite Catalyst for Highly Chemoselective Reductions of Unsaturated Aldehydes",

Chem. Eur. J., 2013, 19, 5255-5258.

T. Mitsudome, M. Matoba, T. Mizugaki, K. Jitsukawa, K. Kaneda

http://onlinelibrary.wiley.com/doi/10.1002/chem.201204160/abstract


 

 3) "Conceptual Design of Metal-Ligand Core-Shell Nanocomposite Catalyst for the Selective Semihydrogenation of Alkynes",

Angew. Chem. Int. Ed., 2013, 52, 1481-1485.

T. Mitsudome, Y. Takahashi, S. Ichikawa, T. Mizugaki, K. Jitsukawa, K. Kaneda

http://onlinelibrary.wiley.com/doi/10.1002/anie.201207845/abstract

2)"Simple and Clean Synthesis of Ketones from internal Olefins Using PdCl2/DMA Catalyst System"

Tetrahedron Lett., 2013, 54, 1596-1598.

T. Mitsudome, S. Yoshida, Y. Tsubomoto, T. Mizugaki, K. Jitsukawa, K. Kaneda

http://dx.doi.org/10.1016/j.tetlet.2013.01.049

 

 


 

1) "Gold Nanoparticle-Catalyzed Cyclocarbonylation of 2-Aminophenols",

Green Chem.,2013, 15, 608-611.

A. Noujima, T. Mitsudome, T Mizugaki, K Jitsukawa, K. Kaneda

http://pubs.rsc.org/en/content/articlelanding/2012/GC/C2GC36851J

 2012年

11) "Investigation of Size-dependent Properties of Sub-nanometer Palladium Clusters Encapsulated within a Polyamine Dendrimer", Chem. Commun., 49, 167-169, (2013).

T. Kibata, T. Mitsudome, T. Mizugaki, K. Jitsukawa, K. Kaneda

http://pubs.rsc.org/en/content/articlelanding/2013/cc/c2cc37038g

 

10) "Selective Hydrogenolysis of Glycerol to 1,3-Propanediol Catalyzed by Pt Nanoparticles-AlOx/WO3", Chem. Lett., 41, 1720, (2012).

T. Mizugaki, T. Yamakawa, R. Arundhathi, T. Mitsudome, K. Jitsukawa, K. Kaneda

https://www.jstage.jst.go.jp/article/cl/41/12/41_CL-121019/_article

 

9) "Highly Efficient Double-Carbonylation of Amines to Oxamides Using Gold Nanoparticle Catalysts", Chem. Commun., 48, 11733, (2012).

T. Mitsudome, A. Noujima, T Mizugaki, K Jitsukawa, K. Kaneda

http://pubs.rsc.org/en/content/articlelanding/2012/cc/c2cc36636c

Selected in Back Cover !

http://pubs.rsc.org/en/content/articlelanding/2012/cc/c2cc90406c

 


 

 

8) "Intermolecular Cyclization of  γ-Acetylenic Acids Using Dendrimer-encapsulated Pd Catalysts"

Z. Maeno, T. Mitsudome, T. Mizugaki, K. Jitsukawa, K. Kaneda Heterocycles, in press.

7)"Titanium Cation-exchanged Montmorillonite as an Active Heterogeneous Catalyst for the Beckmann Rearrangement under Mild Reaction Conditions,

T. Mitsudome, T. Matsuno, S. Sueoka, T. Mizugaki, K. Jitsukawa, K. Kaneda Tetrahedron Lett., 53, 5211-5214(2012).

http://www.sciencedirect.com/science/article/pii/S0040403912011987

6) "Novel Catalysis in Internal Nanocavity of Polyamine Dendrimer for Intramolecular Michael Reaction"

Z. Maeno, T. Mitsudome, T. Mizugaki, K. Jitsukawa, K. Kaneda Chem. Lett., 41, 801-803 (2012).

https://www.jstage.jst.go.jp/article/cl/41/8/41_CL-120239/_article

 

 

 

5) "Unique Catalysis of Gold Nanoparticles in the Chemoselective Hydrogenolysis with H2"

A. Noujima, T. Mitsudome, T. Mizugaki, K. Jitsukawa, K. Kaneda Chem. Commun., 48, 6723-6725 (2012).

http://pubs.rsc.org/en/content/articlelanding/2012/cc/c2cc32850j

 

4) "Highly Efficient Condensation of Glycerol to Cyclic Acetals Catalyzed by Titanium-Exchanged Montmorillonite"

T. Mitsudome, T. Matsuno, S. Sueoka, T. Mizugaki, K. Jitsukawa,  K. Kaneda Heterocycles 84, 371-376, (2012).

http://www.heterocycles.jp/library/abstract.php?doi=21934




3) "Direct Synthesis of Unsymmetrical Ethers from Alcohols Catalyzed by Titanium Cation-exchanged Montmorillonite"
T. Mitsudome, T. Matsuno, S. Sueoka, T. Mizugaki, K. Jitsukawa, K. Kaneda Green Chem. 14, 610, (2012).

http://pubs.rsc.org/en/Content/ArticleLanding/2012/GC/c2gc16135d



2) “Design of a Silver–Cerium Dioxide Core–Shell Nanocomposite Catalyst for Chemoselective Reduction Reactions”

T. Mitsudome, Y. Mikami, M. Matoba, T. Mizugaki, K. Jitsukawa, K. Kaneda Angew. Chem. Int. Ed. 51, 136-139, (2012). 

Selected in Very Important Paper !

http://onlinelibrary.wiley.com/doi/10.1002/anie.201106244/abstract

Selected in Back Cover !

http://onlinelibrary.wiley.com/doi/10.1002/anie.201107546/abstract




1) "Rhodium-Grafted Hydrotalcite Catalyst for Heterogeneous 1,4-Addition Reaction of Organoboron Reagents to Electron Deficient Olefins"

K. Motokura, N. Hashimoto,T. Hara,T. Mitsudome,T. Mizugaki,K. Jitsukawa, Ki. Kaneda Green Chem. 13, 2416-2422, (2012).

http://pubs.rsc.org/en/Content/ArticleLanding/2011/GC/c1gc15146k



2011年

6) “Gold Nanoparticle-catalyzed Environmentally Benign Deoxygenation of Epoxides to Alkenes”, Molecules 16, 8209-8227, (2011).

A Noujima, T Mitsudome, T Mizugaki, K Jitsukawa, K. Kaneda

http://www.mdpi.com/1420-3049/16/10/8209/



5) "Reversible Dehydrogenation-Hydrogenation of Tetrahydroquinoline-quinoline Using a supported Copper Nanoparticle Catalyst", Heterocycles 82, 1371-1377, (2011).

Y. Mikami, K. Ebata, T. Mitsudome, T Mizugaki, K Jitsukawa, K. Kaneda


4) “Highly Efficient Pd/SiO2-Dimethyl Sulfoxide Catalyst System for Selective Semihydrogenation of Alkynes”, Chem. Lett. 40, 405-407, (2011).

Y. Takahashi, N. Hashimoto, T. Hara, S. Shimazu, T. Mitsudome, T Mizugaki, K Jitsukawa, K. Kaneda

http://www.jstage.jst.go.jp/article/cl/40/4/40_405/_article



3) “Selective Deoxygenation of Epoxides to Alkenes with Molecular Hydrogen Using Hydrotalcite-supported Gold Catalyst: A Concerted Effect between Basic Sites and Gold Nanoparticles”, Angew. Chem. Int. Ed. 50, 2986-2989, (2011).

A Noujima, T Mitsudome, T Mizugaki, K Jitsukawa, K. Kaneda

http://onlinelibrary.wiley.com/doi/10.1002/anie.201007679/full

(highlighted at the Hot Paper ! )



2) “Highly Efficient Gold Nanoparticle-Catalyzed Deoxygenation of Amides, Sulfoxides and Pyridine N-Oxides”, Chem. Eur. J. 17, 1768-1772, (2011).

Y. mikami, A Noujima, T Mitsudome, T Mizugaki, K Jitsukawa, K. Kaneda

http://onlinelibrary.wiley.com/doi/10.1002/chem.201003109/full



1) "Subnanoscale Size Effect of Dendrimer-encapsulated Pd Clusters on Catalytic Hydrogenation of Olefin ", Chem. Lett. 40, 180-181, (2011).

 Z. Maeno, T. Kibata, T Mitsudome, T Mizugaki, K Jitsukawa, K. Kaneda

http://www.jstage.jst.go.jp/article/cl/40/2/40_180/_article




2010年

10) “Creation of High-Valent Manganese Species on Hydrotalcite and Its Application to Catalytic Aerobic Oxidation of Alcohols”, Green Chem. 12, 2142-2144, (2010).

S. Sueoka, T Mitsudome, T Mizugaki, K Jitsukawa, K. Kaneda

http://pubs.rsc.org/en/Content/ArticleLanding/2010/GC/c0gc00506a




9) "Supported Monomeric Vanadium Catalyst for Dehydration of Amides to Form Nitriles", Chem. Commun. 46, 8243-8245, (2010).

K. Nagashima, T Mitsudome, T Mizugaki, K Jitsukawa, K. Kaneda

http://pubs.rsc.org/en/Content/ArticleLanding/2010/CC/c0cc02412k



8) "Selective Deoxygenation of Styrene Oxides under a CO Atmosphere Using Silver Nanoparticle Catalyst", Tetrahedron Lett. 51, 5466-5468, (2010).

Y. mikami, A Noujima, T Mitsudome, T Mizugaki, K Jitsukawa, K. Kaneda

http://www.sciencedirect.com/science/article/pii/S0040403910014516



7) "Room Temperature Deoxygenation of Epoxides with CO Catalyzed by Hydrotalcite-supported Gold Nanoparticles in Water", Chem. Eur. J. 16, 11818-11821, (2010).

T Mitsudome, A Noujima, Y. mikami, T Mizugaki, K Jitsukawa, K. Kaneda

http://onlinelibrary.wiley.com/doi/10.1002/chem.201001387/full



6) "Fine Tuning of Pd0 Nanoparticle Formation on Hydroxyapatite and Its Application for Regioselective Quinoline Hydrogenation", Chem. Lett. 39, 832-834, (2010).

N. Hashimoto, Y. Takahashi, T. Hara, S. Shimazu, T. Mitsudome, T Mizugaki, K Jitsukawa, K. Kaneda

http://www.jstage.jst.go.jp/article/cl/39/8/39_832/_article


5) "Creation of a Monomeric Vanadate Species in an Apatite Framework as an Active Heterogeneous Base Catalyst for Michael Reactions in Water ", Catal. Today 152, 93-98, (2010).

K. Kaneda, T. Hara, N. Hashimoto, T. Mitsudome, T Mizugaki, K Jitsukawa

http://www.sciencedirect.com/science/article/pii/S0920586109005756


4) "Supported Gold and Silver Nanoparticles for Green Catalytic Deoxygenation of Epoxides into Alkenes ", Angew. Chem. Int. Ed. 49, 5545-5548, (2010).

T Mitsudome, A Noujima, Y. mikami, T Mizugaki, K Jitsukawa, K. Kaneda

http://onlinelibrary.wiley.com/doi/10.1002/ange.201001055/full

(highlighted at the inside cover ! )

http://onlinelibrary.wiley.com/doi/10.1002/anie.201002977/abstract



3) "Wacker-Type Oxidation of Internal Olefins Using a PdCl2/N,N-Dimethylacetamide Catalyst System under Copper-Free Reaction Conditions ", Angew. Chem. Int. Ed. 49, 1238-1240, (2010).

T Mitsudome, K. Mizumoto, T Mizugaki, K Jitsukawa, K. Kaneda

http://onlinelibrary.wiley.com/doi/10.1002/anie.200905184/abstract

(Selected for VIP and Cover Picture! )

http://onlinelibrary.wiley.com/doi/10.1002/anie.201000112/abstract




2) "Highly Chemoselective Reduction of Nitroaromatic Compounds Using a Hydrotalcite-supported Silver Nanoparticle Catalyst under a CO Atmosphere ", Chem. Lett. 39, 223-225, (2010).

Y. mikami, A Noujima, T Mitsudome, T Mizugaki, K Jitsukawa, K. Kaneda

http://www.jstage.jst.go.jp/article/cl/39/3/39_223/_article



1) "Complete Hydrodechlorination of DDT and Its Derivatives Using a Hydroxyapatite-Supported Pd Nanoparticle Catalyst ", Chem. Lett. 39, 49-51, (2010).

N. Hashimoto, T. Hara, S. Shimazu, Y. Takahashi, T. Mitsudome, T Mizugaki, K Jitsukawa, K. Kaneda

http://www.jstage.jst.go.jp/article/cl/39/1/39_49/_article



総説・著書

3) 「リサイクル型固定化Pd触媒の開発」 クロスカップリング反応 基礎と産業応用、シーエムシー出版 p. 180-190.

2) “Development of Heterogeneous Olympic Medal Metal Nanoparticle Catalysts for Environmentally Benign Molecular Transformations Based on the Surface Properties of Hydrotalcite”, Molecules, 15, 8988-9007, (2010).

1) "Green Catalysis", in Encyclopedia of Catalysis, 2nd edition, I. T. Horvath, Ed., John Wiley & Sons, Inc. in press.

 

2009年
6) "Oxidant-Free Lactonization of Diols Using Hydrtalcite-Supported Copper Catalsyts ", Heterocycles 80, 855-861, (2009).

Y. Mikami, K. Ebata, T. Mitsudome, T Mizugaki, K Jitsukawa, K. Kaneda


5) "Controlled Synthesis of Pd Clusters in Subnanometer Range Using Poly(propylene imine) Dendrimers ", Chem. Lett. 38, 1118-1119, (2009).

T Mizugaki, T. Kibata, K. Ota, T. Mitsudome,  K Jitsukawa, K. Kaneda

http://www.jstage.jst.go.jp/article/cl/38/11/38_1118/_article


4) "Efficient Aerobic Oxidation of Alcohols using a Hydrotalcite-Supported Gold Nanoparticle Catalyst ", Adv. Synth. Catal. 351, 1890-1896, (2009).

T. Mitsudome, A. Noujima, T Mizugaki, K Jitsukawa, K. Kaneda


3) "Supported Gold Nanoparticle Catalyst for the Selective Oxidation of Silanes to Silanols in Water ", Chem. Commun. 5302-5304, (2009).

T. Mitsudome, A. Noujima, T Mizugaki, K Jitsukawa, K. Kaneda


2) "Supported Silver Nanoparticle Catalyst for Selective Hydration of Nitriles to Amides in Water", Chem. Commun. 3258-3260, (2009).

T. Mitsudome, Y. Mikami, T. Mizugaki, K Jitsukawa, K. Kaneda


1) "Supported Gold Nanoparticles as a Reusable Catalyst for Synthesis of Lactones from Diols Using Molecular Oxygen as an Oxidant under Mild Conditions", Green Chem. 11, 793-797, (2009).

T. Mitsudome, A. Noujima, T Mizugaki, K Jitsukawa, K. Kaneda

(highlighted at the inside cover ! )

総説・著書
2) "Design of Well-Defined Active Sites on Crystalline Materials for Liquid-Phase Oxidations", in Modern Heterogeneous Oxidation Catalysis: design, reactions, and characterization, N. Mizuno, Ed., Wiley-VCH, Weinheim, 157-183, (2009).
1) "Development of Concerto Metal Catalysts Using Apatite Compounds for Green Organic Syntheses", Energy & Environmental Science, 2, 655-673, (2009).

2008年
7) "Indium Catalysts for Additions of 1,3-Dicarbonyl Compounds to Unactivated Alkynes Affected by Structure and Acid Strength of Solid Supports", Green Chem. 10, 1231-1234 (2008).
6) "Supported Silver-nanoparticle-catalyzed Highly Efficient Aqueous Oxidation of Phenylsilanes to Silanols.", Angew. Chem. Int. Ed. 47,7938-7940 (2008).
5) "Reusable Montmorillonite-entrapped Organocatalyst for Asymmetric Diels-Alder Reaction", Tetrahedron Lett. 49(38), 5464-5466 (2008).
4) "Copper Nanoparticles on Hydrotalcite as a Heterogeneous Catalyst for Oxidant-free Dehydrogenation of Alcohols", Chem. Commun. (39) 4804-4806 (2008).
3) "Hydrotalcite-bound Ruthenium as a Multifunctional Heterogeneous Catalyst for One-pot Synthesis of a-Alkylated Nitriles and Quinolines", Research on Chemical Intermediates, 34(5-7), 475-486 (2008).
2) "PAMAM Dendron-Stabilised Palladium Nanoparticles: Effect of Generation and Peripheral Groups on Particle Size and Hydrogenation Activity", Chem. Commun. 241-243 (2008).
1) "Oxidant-Free Alcohol Dehydrogenation Using a Reusable Hydrotalcite-Supported Silver Nanoparticle Catalyst", Angew. Chem. Int. Ed. 47,138-141 (2008).

総説・著書
3) 「バナジン酸固定化アパタイト触媒による高効率水中炭素-炭素結合形成反応」、Wako Organic Square, 26(12), 2-4 (2008).
2) 「選択的分子変換反応を可能にする新規機能性固体触媒の開発」、未来材料、8(5)、44-52(2008).
1) 「環境調和型分子変換システムを目指した機能集積固体触媒の創製」、学術月報、61(1)、30-33(2008).

2007年
4) "Magnetically Recoverable Heterogeneous Catalyst: Palladium Nanocluster Supported on Hydroxyapatite-Encapsulated g-Fe2O3 Nanocrystallites for Highly Efficient Dehalogenation with Molecular Hydrogen" Green Chem. 9, 1246-1251(2007).
3) "Nucleophilic Substitution Reactions of Alcohols Using Montmorillonite Catalysts as Solid Bronsted Acids", J. Org. Chem. 72(16), 6005-6016 (2007).
2) "Montmorillonite-Entrapped Sub-nanoordered Pd Clusters as a Heterogeneous Catalyst for Allylic Substitution Reactions", Angew. Chem. Int. Ed.,46(18), 3288-3290 (2007)
1) "Development of Ruthenium-Hydroxyapatite Encapsulated Superparamagnetic g-Fe2O3 Nanocrystallites as an Efficient Oxidation Catalyst by Molecular Oxygen", Chem. Mater. 19(6) 1249-1256 (2007)

総説・著書
5) 「固定化触媒・固定化試薬」 環境化学の事典, IX グリーンケミストリー, 249, pp. 351 (朝倉書店 2007).
4) 「Ru固定化HAP-磁性ナノ粒子ハイブリッド触媒による高効率・高選択的アルコール酸化反応」, Wako Organic Square, 21, 2-4 (2007).
3) 「デンドリマー固定化触媒の開発」、触媒、49(8), 653-658 (2007).
2) 「無機結晶表面を配位子とする固定化金属触媒の創製と環境調和型物質変換反応への展開」, 固定化触媒のルネサンス , 6章, pp. 76-84 (シーエムシー出版 2007).
2) "Opening new avenues for green organic syntheses using heterogeneous metal catalysts", Studies in Surface Science and Catalysis, 172(Science and Technology in Catalysis 2006), 3-10 (2007).
1) "Cation-Exchanged Montmorillonites as Solid Acid Catalysts for Organic Synthesis", Synlett, 7, 999-1015 (2007).

2006年
12) "Efficient C-N Bond Fornations Catalyzed by a Proton-Exchanged Montmorillonite as a Heterogeneous Bronsted Acid", Org. Lett. 8, 4617-4620 (2006).
11) "Highly Efficient C-C Bond-Forming Reactions in Aqueous Media Catalyzed by Monomeric Vanadate Species in an Apatite Framework", J. Org. Chem.. 71, 7455-7462(2006).
10) "Reconstructed Hydrotalcite as a Highly Active Heterogeneous Base Catalyst for Carbon-Carbon Bond Formations in the Presence of Water" J. Org. Chem. 71, 5440-5447 (2006).
9) "Environmentally Friendly One-pot Synthesis of a-Alkylated Nitriles Using Hydrotalcite-Supported Metal Species as Multifunctional Solid Catalysts", Chem. Eur. J. 12, 8228-8239(2006).
8) "Design of High-Performance Heterogeneous Metal Catalysts for Green and Sustainable Chemistry", Bull. Chem. Soc. Jpn., 79, 981-1016 (2006).
7) "A Rhodium-Grafted Hydrotalcite as a Highly Efficient Heterogeneous Catalyst for 1,4-Addition of Organoboron Reagents to a,b-Unsaturated Carbonyl Compounds" Tetrahedron Lett. 47, 5083-5087 (2006).
6) "Highly Efficient Heterogeneous Acylations of Aromatic Compounds with Acid Anhydrides and Carboxylic Acids by Montmorillonite- Enwrapped Titanium as a Solid Acid Catalyst", Res. Chem. Intermed., 32, 305-315 (2006).
5) "Bronsted Acid-Mediated Heterogeneous Addition Reaction of 1,3-Dicarbonyls to Alkenes and Alcohols", Angew. Chem. Int. Ed., 45, 2605-2609 (2006)
4) "A Convenient and Efficient Palladium-Catalyzed Regioselective Oxyfunctionalization of Terminal Olefins by Use of Molecular Oxygen as a Sole Reoxidant", Angew. Chem. Int. Ed., 45, 481-485 (2006)
3) "Creation of Monomeric La Complexes on Apatite Surfaces and Their Application as Heterogeneous Catalysts for Michael Reactions", New J. Chem., 30, 44-52 (2006)
2) "Highly Efficient Wacker Oxidation Catalyzed by Heterogeneous Pd-Montmorillonite under Acid-free Conditions", Tetrahedron Lett., 47, 1425-1428 (2006)
1) "Shape- and Size-Controlled Synthesis of Tetrahedral Pd Nanoparticles Using Tetranuclear Pd Cluster as Precursor", Chem. Lett., 35, 276-278 (2006)

総説
6) "共存する酸・塩基触媒", 化学 61, 72-73 (化学同人, 2006)
5) "グリーンプロセスに向けた環境調和型固定化金属触媒の開発", SPring-8の高輝度放射光を利用した先端触媒開発 第4章, 第2節, 5, 245-252 (エヌ・ティー・エス出版, 2006)
4) "Design of ruthenium catalysts bound to inorganic crystalline materials for environmentally-benign organic synthesis." Current Organic Chemistry 10(2): 241-255.
3) "リサイクル型固定化Pd触媒の開発", ファインケミカル 35,(5), 60-69, (2006).
2) "触媒設計", 第5版 実験化学講座 展開編 25巻 1章 触媒化学の基礎 5節 触媒化学・電気化学, 56-67 (日本化学会, 2006)
1) “クラスター触媒”, ナノマテリアル技術体系 第二巻ナノ金属, 井上 明久 監修, 568-572 (フジ・テクノサービス, 2006)

2005年までの論文



報道情報


以下の雑誌や新聞に我々のグループの研究が紹介されています。

プレス発表

(8) 化学工業日報200781日「Pdナノ粒子三角錐型に」

(7) 化学工業日報2007531日「酸化剤不要の新触媒」

(6) 化学工業日報200445日「高効率に“脱ハロゲン”」

(5) 日刊工業新聞2004326日「PdHAP触媒で脱ハロゲン」

(4) 化学工業日報200211月5日「デンドリマー用い新触媒」

(3) 化学工業日報200271日「原子価3種混在のパラジウム触媒」

(2) 日刊工業新聞2002610日「“エネ効率”常に頭に」

(1) 読売新聞夕刊200251日 緑の化学(グリーンケミストリー)新世紀 (17)
「ホネのある?固体触媒」

ウェブサイト 

ワイリー・サイエンスカフェにて紹介されました。


(2) 大阪大学・金田清臣先生のAngewandte Author Profileを公開(10報目)

http://www.wiley.co.jp/blog/pse/?p=6033


(1) "Design of a Silver–Cerium Dioxide Core–Shell Nanocomposite Catalyst for Chemoselective Reduction Reactions." Angewandte Chemie International Edition. 2012, 1, 136-139. http://www.wiley.co.jp/blog/pse/?p=3036


Organic-Chemistry.Org. にて紹介されました。

(4) "Highly Efficient C-C Bond-Forming Reactions in Aqueous Media Catalyzed by Monomeric Vanadate Species in an Apatite Framework"
J. Org. Chem., 2006, 71, 7455-7462, http://www.organic-chemistry.org/abstracts/lit1/412.shtm

(3) "Reconstructed Hydrotalcite as a Highly Active Heterogeneous Base Catalyst for Carbon-Carbon Bond Formations in the Presence of Water"
J. Org. Chem., 2006, 71, 5440-5447
, http://www.organic-chemistry.org/abstracts/lit1/326.shtm

(2) "Bronsted Acid Mediated Heterogeneous Addition Reaction of 1,3-Dicarbonyl Compounds to Alkenes and Alcohols"
Angew. Chem. Int. Ed., 2006, 45, 2605-2609, http://www.organic-chemistry.org/abstracts/lit1/211.shtm

(1) "Convenient and Efficient Pd-catalyzed Regioselective Oxyfunctionalization of Terminal Olefins by Using Molecular Oxygen as Sole Reoxidant"
Angew. Chem. Int. Ed., 2006, 45, 481-485, http://www.organic-chemistry.org/abstracts/lit1/080.shtm


ジャーナル

Science誌


(3) "Building a Better Wacker", Editors’ Choice (by Gilbert Chin), Science Dec 16, 2005, 310, 1743.


(2) "To Have and To Hold", Editors’ Choice (by Gilbert Chin),
Science Feb. 6, 2004, 303, 731.

(1) "A Bone-Supported Catalyst", Editors’ Choice (by Gilbert Chin), Science July 28, 2000, 289, 509


Angew. Chem. Int. Ed誌


(2) 金田先生 Author Profile (2012年3月15日)

http://onlinelibrary.wiley.com/doi/10.1002/anie.201200634/abstract


(1) Sequential One-Pot Reactions Using the Concept of "Site Isolation", (by Dr. Brigitte Voit) Angew. Chem. Int. Ed. Published Online: 26 May 2006, DOI: 10.1002/anie.200504353


Green Chemistry誌


(3) "Heterogeneous catalysts for Diels-Alder and aldol reactions", Highlights- Markus Holscher reviews some of the recent literature in green chemistry-, Green Chemistry 2004, G3.

(2) "Oxidation of alcohols", Highlights- Duncan Macquarrie highlights some of the recent literature in green chemistry-,
Green Chemistry 2002, G56.

(1) "Hydroxyapatite", Highlights- Duncan Macquarrie highlights some of the recent literature in green chemistry-, Green Chemistry 2002, G55.


Synfact誌

(9) Deoxygenation of amides, sulfoxides, and pyridine N-oxides with AuHAP, Synfacts, 2011, 5, 568

(8)
Dehydration of amides with hydrotalcite-supported vanadium catalyst, Synfacts, 2011, 2, 228

(7) Deoxygenation of epoxides with hydrotalcite-supported silver nanoparticles, Synfacts, 2010, 12, 1441.

(6) Hydrogenation of quinolines using Pd0 nanoparticles on hydroxyapatite,Synfacts, 2010, 11, 1316.

(5) Palladium-catalyzed copper-free Wacker Oxidation of Internal Olefins,Synfacts, 2010, 4, 468.

(4) Oxidation of Silanes with AuHAP in Water,Synfacts, 2009, 12, 1412
.

(3) Aerobic Oxidation of Alcohols with Au/HT,Synfacts, 2009, 10, 1288.

(2) Hydration of Nitriles to Amides with Supported Silver Nanoparticles,Synfacts, 2009, 10, 1167.

(1) Asymmetric Diels-Alder Reaction Using a Montmorillonite-Entrapped Organocatalyst,Synfacts, 2008, 11, 1231


CHEMTEC誌



(2) "Catalyze the efficient epoxidation of olefins with H2O2 by using layered hydrotalcite", W. Jerry Patterson, CHEMTECH 1998, September, 56.

(1) "The oxidation of ketones to lactones or esters using m-chloroperoxybenzoic acid (m-CPBA)", B. S. Thyagarajan,
CHEMTECH 1997, January, 4.


A Dual-functional Heterogeneous Ruthenium Catalyst for the Green One-pot Synthesis of Biphenols