GRATAMA WORKSHOP 2000
Scientific Program
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April 21 (Fri)
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[Icho-Kaikan]
10:00 Registration
12:00-13:30 Lunch
<Chairpersons: Prof. S. Murai and Prof. E. Drent>
13:30 -14:30 Director Dr. Tetsuo Shiba (Peptide Institute; Emeritus Professor, Osaka Univ.)
Contributions of Dutch Scientists in Modernization of Osaka
14:30 -14:50 Coffee Break
14:50 -15:50 Prof.Dr.Ir. Jakob de Swaan Arons (Delft Univ. of Tech.)
Thermodynamics. Key Discipline for the Design of a Sustainable Society
15:50-16:50 Prof.Dr. Shun-Ichi Murahashi (Osaka Univ.), President of The Chem. Soc. Japan
Exploitation of Environmentally Friendly Catalytic Processes
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[Senri-Hankyu Hotel]
18:30- Banquet
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April 22 (Sat)
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[Osaka International Convention Center]
9:00-9:50 Opening Ceremony
9:00; Opening Remarks (Dr. T. Kishimoto, President of Osaka University )
9:05; Greetings (Dr. Nicolas de Voogd, President of Delft University of Technology )
9:10; Key note address (Ms. A. Jorritsma, Deputy Prime Minister, Minister for Economic Affairs)
9:25; Lecture (Prof. Emeritus T. Shiba)
Koenraad Wolter Gratama, founding father of chemistry in Japan
9:40; Unveiling ceremony of the GRATAMA bust
( His Royal Highness the Prince of Orange )
9:50; Closing
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10:30-17:00 Bus Tour
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[Kanrin-Maru ship in Osaka Harbour]
17:00-19:30 Reception
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April 23 (Sun) [Icho-Kaikan]
<Chairpersons: Prof. J. Schoonman and Dr. M. Haruta>
9:00-10:00 Prof.Dr.Ir. Herman van Bekkum (Delft Univ. of Tech.)
From Fossil to Green. The Increasing Role of Renewables as organic Raw
Materials
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10:00 -10:10 Coffee Break
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10:20 -11:20 Director-General Dr. Teruo Kodama (Electrotechnical Lab., AIST)
Future Prospects of Fuel Cell Technology
11:20 -12:20 Dr.Ir. Michiel J. Groeneveld (Shell Res. and Tech. Centre)
Research for a SUSTAINABLE Shell
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12:20-14:00 Lunch on Seminar <Chairperson: Prof. J. de Swaan Arons >
Prof. Dr. Alle Bruggink (DSM Research, University of Nijmegen)
Sustainable Technology Research at DSM
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<Chairpersons: Prof. S.J. Heijnen and Dr. Y. Sawada>
14:00-16:00 Short Introductory Presentations for Posters
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16:00 -16:55 Poster Session (Coffee Bar)
Odd numbers
16:55 - 17:05 Group photograph
17:05-18:00 Even numbers
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April 24 (Mon) [Icho-Kaikan]
<Chairpersons: Prof. Y. Hirata and Prof. J.A. Moulijn>
9:00-10:00 Vice-Rector Dr. Motoyuki Suzuki (The United Nations Univ.)
Realization of a Sustainable Society through Zero-Emission Approaches
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10:00-10:20 Coffee Break
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10:20-11:20 Prof.Dr. Gerard van Koten (Utrecht Univ.)
Metallo-dendrimers as Multisite Homogeneous Catalysts
11:20-12:20 Prof.Dr. Egbert W. Meijer (Technical Univ. of Eindhoven)
Hierarchical growth of supramolecular architectures;
Towards functional materials for solar cells
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12:20-14:00 Lunch
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14:00-17:20 Session Presentations
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Session A : Chemical Technology for Energy and the Environment
<Chairpersons: Prof. H. van Bekkum and Prof. I. Komasawa>
14:00-15:00 Prof.Dr. Joop Schoonman (Delft Univ. of Tech.)
Nanostructured Materials for Renewable Energy Conversion and Storage Systems
15:00-16:00 President Dr. Akira Ohta (Panasonic EV Energy Co.)
EV (Electric Vehicle) Batteries - State-of-affairs and future prospect -
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16:00-16:20 Coffee Break
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16:20-17:20 Prof.Dr. Jacob A. Moulijn (Delft Univ. of Tech.)
The Potential of Monolithic Reactors in the Chemical Industry
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Session B : Precision Chemistry and Catalysis
<Chairpersons: Prof. S. Shinkai and Prof. E. W. Meijer>
14:00-15:00 Prof.Dr. Eite Drent (Shell Res. Tech. Centre and Leiden University)
Adventures in Homogeneous Catalysis by Cationic Palladium Complexes
15:00-16:00 Prof.Dr. Masakazu Anpo (Osaka Prefecture Univ.)
The Design and Development of Second-Generation Titanium Oxide Photocatalysts to Better
Our Environment Approaches in Realizing the Use of Visible Light
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16:00-16:20 Coffee Break
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16:20-17:20 Prof.Dr.Ir. David N. Reinhoudt (Twente Univ.)
Supramolecular Materials
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Session C : Green Chemistry
<Chairpersons: Prof. W.P.M. van Swaaij and Prof. K. Miyamoto>
14:00-15:00 Dr. Shin-ya Yokoyama (Natl. Inst. for Resources and Environment, AIST)
Oil Production from Biomass Resources by Thermochemical Process
15:00-16:00 Prof.Dr.Ir. Sef J. Heijnen (Delft Univ. of Tech.)
Microorganisms as Micro-Chemical Factories for Sustainable Precision Production of
Chemicals
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16:00-16:20 Coffee Break
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16:20-17:20 Prof.Dr. Tadayuki Imanaka (Kyoto Univ.)
Biological Oil Production from CO2
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[Senri-Hankyu Hotel]
18:30 - Farewell party
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April 25 (Tue) [Icho-Kaikan]
<Chairpersons: Prof. G. van Koten and Prof. S. Kusumoto >
9:00-10:00 Prof.Dr. Yoshihiko Ito (Kyoto Univ.)
Screw-sense Selective Polymerization of ortho-Diisocyanobenzenes Catalyzed by Chiral
Palladium Complexes Synthesis of Optically Active Poly(2,3-quinoxaline)s
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10:00-10:20 Coffee Break
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10:20-11:20 Prof.Dr.Ir. Wim P.M. van Swaaij (Twente Univ.)
Thermochemical processes for the conversion of biomass to secondary energy carriers: a review
11:20 -12:20 Prof.Dr. Yasuhiro Iwasawa (Univ. of Tokyo)
Atom-resolved Chemistry at Catalyst and Model Surfaces
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12:20-12:50 Closing Remarks
Dr. J. Veldhuis, President of Utrecht Univ.
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Poster Sessions
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- Area A : Chemical Technology for Energy and the Environment-
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A-01 Exergetic Life Cycle Analysis
Ren L. Cornelissen, Lex van Nimwegen, Gerard Hirs
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A-02 Photovoltaic Solar Cells: a New Approach
Albert Goossens and Joop Schoonman
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A-03 On the Efficiency and Sustainability of the Process Industry
A. P. Hinderink, H. J. van der Kooi and J. de Swaan Arons
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A-04 Novel Refining Processes for Fuel Oil by Photochemical Reaction
and Liquid-Liquid Extraction
Takayuki Hirai, Yasuhiro Shiraishi and Isao Komasawa
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A-05 A Carbon Dioxide Gas Sensing for a Global Monitoring
Nobuhito Imanaka and Gin-ya Adachi
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A-06 Membrane Reactor Technology for CPO, Air Separation
and Fuel Processing
G. J. Kramer, J. de Swaan Arons, H. J. van der Kooi,
W. P. M. van Swaaij, H. Verweij, K. P. de Jong
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A-07 Alternative Routes for Ethanol Production from Renewable Resources
J. Mulder, J. Dewulf, H.J. van der Kooi, J. de Swaan Arons
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A-08 Microporous and Mesoporous Inorganic Membranes with Uniform Pores
N. Nishiyama, D.-H. Park, Y. Egashira and K. Ueyama, L. Gora,
F. Kapteijn and J. A. Moulijn
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A-09 Water Splitting by Electrochemical Combination of Two
Photocatalytic Reaction Systems
Teruhisa Ohno, Kan Fujihara, and Michiko Matsumura
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A-10 Optical and InfraRed Imaging of Growing Polypropylene Particles
Jochem T.M. Pater, Gnter Weickert and Wim P.M. van Swaaij
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A-11 Safety of Lithium Battery with Brannerite-Type LiMoVO6 as
a Cathode Material
Hikari Sakaebe, Masahiro Shikano, Yongyao Xia,
and Tetsuo Sakai
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A-12 Human-Cell-Based Bioassay for the Environmental Risk Management
Y. Sakai, R. Shoji, B.-S. Kim, T. Fujii, A. Sakoda and M. Suzuki
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A-13 High-Surface-Area Electrocatalysts for Polymer Electrolyte Fuel Cells
Kazuaki Yasuda
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A-14 High Power Ni-MH Battery for Electric Vehicle
Shin-ichi Yuasa, Tetsuo Nanno
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A-15 Covalently Attached Monolayers on Silicon Surfaces
Han Zuilhof
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- Area B : Precision Chemistry and Catalysis-
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B-01 Homogeneous and Heterogeneous Catalysis with Metal-Containing
Silsesquioxanes
Hendrikus C. L. Abbenhuis
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B-02 Two Reactions of Allylic Alcohols Catalysed by Ruthenium
Cyclopentadienyl Complexes with Didentate Phosphine Ligands:
Isomerisation and Ether Formation
Elisabeth Bouwman, Robert C. van der Drift, Eite Drent
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B-03 Low Cost Nickel-Based Catalyst for Polyketone Synthesis
J. K. F. Buijink, E. Drent, J. C. L.J. Suykerbuyk, M. C. T. de Cock
and L. Schoon
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B-04 Ru3(CO)12-Catalyzed Decarbonylative Cleavage of a C-C Bond
of Alkyl Phenyl Ketones
Naoto Chatani, Yutaka Ie, Fumitoshi Kakiuchi, and Shinji Murai
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B-05 Shape-Selective Meerwein-Ponndorf-Verley Reductions and
Oppenauer Oxidations Catalysed by Zeolite Beta
E. J. Creyghton and H. van Bekkum
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B-06 Lifetime and Association Constant of 2-ureido-4[1H]-
Pyrimidinone Dimers
M. H. P. van Genderen, S. H. M. Sntjens, R. P. Sijbesma
and E. W. Meijer
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B-07 Combining Catalytic Olefin Polymerization and C-H Bond
Activation: Synthesis of 2-Thienyl end-Functionalized Polyethene
with a Lanthanocene Catalyst
Bart Hessen, Stphanie N. Ringelberg, Auke Meetsma
and Jan H. Teuben
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B-08 Self-Assembly in 2D and 3D; a Powerful Tool for Nanotechnology
Wilhelm T. S. Huck, Leonard Prins, Frank C. J. M. van Veggel,
David N. Reinhoudt, Lin Yan, Abe Stroock, and George M. Whitesides
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B-09 Nanotechnology at Interfaces: Isolated Nanosize Molecules
Bart-Hendrik Huisman, A. Friggeri, F. C. J. M. van Veggel,
and D. N. Reinhoudt
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B-10 Copper-Catalyzed Aerobic Oxidation of Alkanes
Naruyoshi Komiya, Tatsuyuki Kumano,
and Shun-Ichi Murahashi
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B-11 Monitoring Catalytic Events on a Millisecond Time Scale
Using MultiTrack
G. Mul, A. D. van Langeveld, A. Zwijnenburg, A. Vaccaro,
T. A. Nijhuis, and J. A. Moulijn
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B-12 Controlled Carbon-Carbon Bond Cleavage of Cyclobutanone
Masahiro Murakami, Tamon Itahashi, Takuo Tsuruta,
and Yoshihiko Ito
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B-13 Monolithic Catalysts as Efficient Reactors in Three-Phase
Applications
T. A. Nijhuis, F. Kapteijn, and J. A. Moulijn
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B-14 Molecular Simulations on Zeolites to Understand Their
Behaviour as Catalysts
S. L. Njo, B. van de Graaf , H. van Koningsveld
and H. van Bekkum
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B-15 Asymmetric Synthesis Polymerization of C1 Resources
Kyoko Nozaki, Yasutoyo Kawashima, Koji Nakano,
and Tamejiro Hiyama
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B-16 Transition Metal-Catalyzed Enantioselective Reactions in Water
Using Water-Soluble Chiral Ligands Derived from Natural Sugars
Kouichi Ohe, Koji Yonehara, Tomohiro Hashizume, Kenji Mori,
and Sakae Uemura
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B-17 H/D Isotope Exchange as a Tool for Characterising Acid Catalysts
M. S. Rigutto, J. A. R. van Veen, C. A. Emeis,
and Th. L. M. Maesen
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B-18 Integration of Biocatalysis and Transition Metal Catalysis:
Trifunctional Amino Acids and Applications
Floris P. J. T. Rutjes
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B-19 Energy Transfer in Supramolecular Assemblies of
Oligo(p-phenylene vinylene)s Terminated Poly(propylene imine)
Dendrimers
A. P. H. J. Schenning
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B-20 Structure and Unique Catalysis of Mo Dimer Oxycarbides
Entrapped in NaY Zeolite Supercages
T. Shido, F. Nakagawa, Y. Noguchi, K. Asakura,
and Y. Iwasawa
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B-21 Transition-Metal Catalyzed Access to New Organic Compounds
Incorporating Silicon and Boron
Michinori Suginome
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B-22 Iridium-Catalyzed Addition of Carbon Pronucleophiles to
CN Triple Bonds of Nitriles
Hikaru Takaya and Shun-Ichi Murahashi
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B-23 Ru3(CO)12-Catalyzed [2 + 2 + 1] Cycloaddtion of Ketones, Olefins,
and Carbon Monoxide Leading to Functionalized g-Butyrolactones
Mamoru Tobisu, Naoto Chatani, Taku Asaumi, Yoshiya Fukumoto,
and Shinji Murai
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B-24 Learning from the Architecture of Nature to Design Chemical
Processes from the Molecular to the Reactor Scale
Marc-Olivier Coppens
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- Area C : Green Chemistry -
C-01 Novel Microbial Enzymes Involved in the Biological Fixation of
Carbon Dioxide
Haruyuki Atomi and Tadayuki Imanaka
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C-02 Saccharomyces Cerevisiae as a Multi-Purpose Cell Factory
Barbara M. Bakker, Johannes P. van Dijken en Jack T. Pronk
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C-03 Protein Engineering: a Versatile Method for the Preparation of
Bio-Inspired Materials
J. C. M. van Hest, K. L. Kiick, and D. A. Tirrell
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C-04 Application of Green Algae for Clean Environment - Removal of
Air Pollutants and Conversion of Algal Biomass to Useful Compounds
Kazumasa Hirata, Hiroyasu Nagase, and Kazuhisa Miyamoto
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C-05 Catalytic Reduction of Nitrogen Oxides in Diesel Exhaust Gases
with Ce-Zeolites
Eri Ito, W. van Kooten, C.M. van den Bleek and H. van Bekkum
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C-06 Material Engineering toward Sustainable Global System
-Approach through Green Chemistry-
Osamu Kitao
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C-07 Production of PHA (poly hydroxyalkanoate) by Genetically
Engineered Marine Cyanobacterium
Hitoshi Miyasaka, Hideo Akiyama
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C-08 Thermophilic Bacteria Isolated from a Subterranean Petroleum
Reservoir
Masaaki Morikawa, Tomohisa Kato, Mitsuru Haruki,
Tadayuki Imanaka, and Shigenori Kanaya
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C-09 Development of Novel Biodegradable Polyesters and
Their Safety Assessment
A. Nakayama, N. Kawasaki, N. Yamamoto and S. Aiba
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C-10 Establishment of a Thermostable Photo-Induced Hydrogen
Production System.
Masahiro Takagi, Keiko Minami, Tamotsu Kanai,
and Tadayuki Imanaka
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C-11 Novel Homogeneous Hydrogenation of Carbon Dioxide Using
Tetranuclear Ruthenium Cluster Complex
Ken-ichi Tominaga and Yoshiyuki Sasaki
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C-12 Design of Stimuli-Responsive Artificial Chaperone for the
Development of Stress-Mediated Nano Green Bioprocess
Hiroshi Umakoshi and Ryoichi Kuboi
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C-13 Sparkling, Generic Technologies for the Large Scale Manufacturing
and Application of Protein-Based Structures for Biopharmaceuticals,
Structured Foods, Separation Media and Novel Materials
L. A. M. van der Wielen, M. O. Coppens, and G. J. Witkamp
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